Top casting tips:
Use a syringe to measure out silicon catalyst :duh:
Buy a box of wooden mixing sticks (like big lollipop sticks) from Tiranti. Essential for mixing rubber and resin. You can reuse the ones you mix resin with. A box lasts years!
I found silicon easiest to mix properly in a wide and shallow container.
I used to mix resin in 100g batches in plastic cups. I weighed out the correct amount of part A into a cup using digital scales and marked it on the side of the cup. I added the right amount of part B and marked the level again. Keep that cup and use it as visual reference for pouring by eye. If you get the cups with rings around the outside they help loads. A stick marked with the correct levels is useful too. This saves lots of time. And scales.
If you leave your mixing sticks to set in the dregs of resin in your plastic cups the whole lot will pull away from the plastic when the resin sets, leaving perfectly clean cups for you to reuse. You also get cup-shaped castings to throw at your spouse
Dust your plasticine (and masters!) with talcum powder or French chalk before you press your masters into it. Use proper mould release spray before pouring your silicon.
Acquire a vacuum chamber if you want to cast resin properly.
HTH!